In article the existing lows and other legislation acts of state regulation in the field of medical maintenance of the works connected to destruction of toxic chemicals concerning to the chemical weapon is analysed. Features of carrying out of medical examinations and expertise of diseases at the soldiers and officers occupied on these works are submitted. The conclusion that the existing legislation acts allows to carry out qualitative medical service of the personnel of objects of storage and destruction of the chemical weapon, the military men occupied on works with toxic chemicals and the inhabitants living in sanitary-protective zones is made.